High-tech adhesives are very reliable and issues do not occur often. When used correctly, these adhesives can resolve many design issues while also saving money, time, and effort. However, there are many potential reasons for a possible failure when using these materials. Failure can be defined as no adhesion upon cure, reduced adhesive strength, or loss of adhesion over time. When any problem occurs, the adhesive is very often one of the first components to be examined. Finding the cause of a failure can sometimes become difficult, especially when a failure is intermittent or it started after a long period of success. There are a number of standard issues that should be considered to determine the cause of a failure.
Contamination should be one of the first considerations. Any grease, oil, or other impurity on the surface can potentially cause loss of adhesion. Dirty substrates are an obvious potential problem, but contamination can be inadvertent. Oils from skin contact, especially on very small parts, could be enough to cause a problem. Components may have been improperly cleaned. Component manufacturers sometimes change a production process that does not affect the component performance or tolerances but can unintentionally affect the bonding of that component. Controlling the cleaning process at the usage site is the best method to ensure occurrence of this potential problem does not arise.
Another possible source of contamination is silicone release agents that can settle onto surfaces and prevent adhesion. Care must be taken to prevent cross contamination if using silicones or any release agent. For this reason, some manufacturing facilities will not allow the use of any silicone compounds.
Surface preparation is essential for bond consistency. There are many methods to prepare surfaces, including washing, abrasion, and plasma/corona treatment. The best surface preparation will depend upon the specific substrate and adhesive chemistry used. Consult with your substrate provider or adhesive manufacturer for the appropriate preparation. Lack of consistent surface preparation can be a big contributor to adhesion issues. (See Figure 1)
Mix ratio for many two-part materials can be a major issue. Some systems are very sensitive to minor changes in the mix ratio. Many materials are stoichiometrically balanced and an off-ratio mix may cause the material to cure erratically and/or not perform to its optimal capability. (See Figure 2)
Even some materials that are not as sensitive to the mix ratio may exhibit slightly different characteristics when the ratio is varied. Materials that do cure with an off-ratio mix may have slightly different finished hardness and tensile strength, thus affecting the final performance.
Mixing of two-part adhesives is a basic process function, but is essential for of these adhesives to work properly. Insufficient mix may result in a partial chemical reaction that leads to partial curing. An insufficiently cured material will most likely result in poor bond strength and lower physical properties.
Also, mixing of the original container can be very important. Fillers or other constituents could settle. Ensuring a homogenous mix of each component prior to mixing (for two parts) is vital to achieve maximum properties.
Application technique can be critical. If material is manually applied, ensure that the amount is consistent for each unit. Most adhesives work best with an appropriate bond line. Too much, or too little, material could produce variable cured strengths. If applicable, make sure that the adhesive is applied in the same location on every component. (See Figure 3)
If automated placement is used, ensure that the equipment is clean when starting and remains clean during use. Some adhesives can partially cure in the dispensing apparatus, thus clogging the unit and preventing a consistent amount of material from being applied to each part. Less adhesive could result in decreased strength.
Air entrapment can be a source of inconsistent failure, especially in small applications. Removal of air from a system, prior to application, may be a necessary processing step. Air gaps could prevent the adhesive from interfacing fully with the substrate surface, which may result in decreased strength.
Incompatibility with substrates can also be a contributor to failure with some adhesives. Certain plastics may contain plasticizers that could seep to the surface over time, causing a bond to fail. This seepage could be inconsistent from lot to lot so that some parts never fail, while others lose adhesion.
Some substrates can actually interfere with the cure mechanism of an adhesive. This is usually an issue that is addressed when selecting the adhesive, but sometimes appears later.
Cure time and temperature can be major factors contributing to incomplete cure and performance of many systems. Some materials must be exposed to certain temperatures in order to cure. The performance of many ovens can vary considerably, thus an adhesive may not seem to cure in its allotted time. Too high a temperature may cause a material to polymerize incorrectly and cause degraded properties.
Some materials may cure at lower temperatures, but not produce the same physical characteristics as when cured with elevated temperatures. Alternatively, certain chemistries designed for low-temperature cure should not be heated when cured.
Products cured with UV energy have the same issues. They must be cured with the correct wavelength and energy level. Certain chemistries will not cure with low light exposure, and others can burn if subjected to high dosage. Some of the UV chemistries must be heat post cured to achieve their maximum performance.
Environmental conditions should also be noted as many materials can be affected by their surroundings. For example, high moisture levels can prevent cure in some materials while it speeds up the reaction in others. Carbon dioxide, pH, oxygen, and environmental temperature could all adversely affect the finished adhesive.
As stated earlier, intermittent problems are the hardest to resolve. These are almost always due to a factor other than the adhesive. Of course a batch of adhesive may have been produced incorrectly, but this is actually very rare as reputable manufacturers use reliable raw materials and process controls to ensure a consistent finished product. Greater than 98 percent of adhesive problems are not due to the adhesive itself, but due to one of the causes previously discussed.
Speaking to experts is always useful. Your supplier should encourage conversation with their technical team to resolve specific problems.
This article was written by Barry Siroka, Business Development Manager, EpoxySet Inc., Lincoln, RI. For more information, Click Here